Home Chemistry Organic Building Blocks Azoes (E)-1-(Naphthalen-1-Yl)-2-Phenyldiazene
Azo Coupling: Diazene compounds can undergo azo coupling reactions, which involve the formation of a new azo bond (N=N) between two diazene molecules. This reaction is commonly used to synthesize azo dyes. In your compound, (E)-1-(naphthalen-1-yl)-2-phenyldiazene, the diazene group may potentially participate in azo coupling reactions with other diazene-containing compounds.
Reduction: Diazene compounds can be reduced to yield hydrazine derivatives. For example, they can be reduced with a reducing agent like sodium borohydride (NaBH4) or hydrogen gas H2 in the presence of a catalyst. The reduction results in the formation of hydrazine and its derivatives.
Diazo Transfer Reactions: Diazene compounds can participate in diazo transfer reactions where the diazene functional group is transformed into a diazonium ion (R-N2+). These reactions are useful in various synthetic transformations, such as the synthesis of aromatic amines and azo compounds.
Azo-Hydrazone Tautomerism: Diazene compounds can exist in equilibrium with their tautomeric hydrazone forms. In this tautomeric transformation, the N=N bond is converted to a C=N bond. This tautomeric equilibrium can be influenced by pH and reaction conditions.
Nitrogen Elimination: Under certain conditions, diazene compounds can undergo nitrogen elimination reactions, leading to the formation of nitrogen gas and the corresponding organic product.
Metalation: The diazene nitrogen atoms can coordinate with metal ions, leading to the formation of metal-diazene complexes. These complexes can participate in various catalytic reactions.
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Sodium 6-hydroxy-5-(phenyldiazenyl)naphthalene-2-sulfonate
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1-((4-Methyl-2-nitrophenyl)diazenyl)naphthalen-2-ol
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