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Chemical Structure| 185690-39-5 Chemical Structure| 185690-39-5

Structure of 185690-39-5

Chemical Structure| 185690-39-5

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Product Details of [ 185690-39-5 ]

CAS No. :185690-39-5
Formula : C66H48N4
M.W : 897.11
SMILES Code : C1(N(C2=C3C=CC=CC3=CC=C2)C4=CC=CC=C4)=CC=C(N(C5=CC=C(N(C6=C7C=CC=CC7=CC=C6)C8=CC=CC=C8)C=C5)C9=CC=C(N(C%10=C%11C=CC=CC%11=CC=C%10)C%12=CC=CC=C%12)C=C9)C=C1
MDL No. :MFCD01310679

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Application In Synthesis of [ 185690-39-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 185690-39-5 ]

[ 185690-39-5 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 90-30-2 ]
  • [ 4181-20-8 ]
  • [ 185690-39-5 ]
YieldReaction ConditionsOperation in experiment
60% With copper; potassium carbonate; In decalin; at 220℃; for 24h; Compound 5; 4,4',4-tris[(1-naphtyl)phenylamino]tripnenylamine; 28.7 g (0.046 moles) of 4,4',4-triiodotriphenylamine, 50.4 g (0.23 moles) of N-(1-naphtyl)aniline, 44.2 g (0.32 moles) of anhydrous potassium carbonate, 4.32 g (0.068 moles) of copper powders and 50 ml of decalin were added to a reaction container of 200 ml, and the mixture was heated in an oil bath at 220° C. for 24 hours in an argon atmosphere. After completion of the reaction, 200 ml of toluene was added to the reaction product, followed by filtering to remove the insoluble. The filtrate was washed with water, and dried on sodium sulfate. After drying, the solvent was evaporated from the filtrate, and the residue was purified four times on a column chromatography using silica gel as a carrier and a mixture of n-hexane and toluene as a developing solvent. The recrystallization process was repeated using a mixture of n-hexane and toluene and ethyl acetate, followed by vacuum drying. 24.7 g (yield: 60.0percent) of 4,4',4-tris[(1-naphtyl)phenylamino]tripnenylamine was obtained. The resulting product was further purified by sublimation to obtain a high purity 4,4',4-tris[(1-naphtyl)phenylamino]tripnenylamine (yield of sublimation purification: 70.0percent).
 

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