189178-09-4|Tris(4-ethynylphenyl)amine| Ambeed

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Quality Control of [ 189178-09-4 ] Purity: 98% SDS Specification

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Product Details of [ 189178-09-4 ]

CAS No. :	189178-09-4
Formula :	C₂₄H₁₅N
M.W :	317.38
SMILES Code :	C#CC1=CC=C(N(C2=CC=C(C#C)C=C2)C3=CC=C(C#C)C=C3)C=C1
MDL No. :	MFCD09030768
InChI Key :	QGICIDGCKPUALM-UHFFFAOYSA-N
Pubchem ID :	23443705

Safety of [ 189178-09-4 ]

GHS Pictogram:
Signal Word:	Warning
Hazard Statements:	H302-H315-H319-H335
Precautionary Statements:	P261-P305+P351+P338

Application In Synthesis of [ 189178-09-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 189178-09-4 ]

[ 189178-09-4 ] Synthesis Path-Downstream 1~35

1
[ 827-15-6 ]
[ 189178-09-4 ]
tris-4,4',4''-(pentafluorophenylethynyl)triphenylamine [ No CAS ]

References: [1]Journal of Organic Chemistry,2005,vol. 70,p. 1134 - 1146.

2
[ 619-44-3 ]
[ 189178-09-4 ]
[ 848568-96-7 ]

References: [1]Journal of Organic Chemistry,2005,vol. 70,p. 1134 - 1146.

3
[ 79887-18-6 ]
[ 189178-09-4 ]
(4-ethynylphenyl)amine]-co-[(4-heptyloxy)phenylacetylene], hyperbranched, M_w: 18200, polydispersity index: 5.3, temperature for 5 percent loss: 456 deg C; monomer(s): tris(4-ethynylphenyl)amine; (4-heptyloxy)phenylacetylene [ No CAS ]

References: [1]Journal of Physical Chemistry B,2004,vol. 108,p. 10645 - 10650.

4
[ 19524-06-2 ]
[ 189178-09-4 ]
[ 359647-66-8 ]

References: [1]Journal of Organic Chemistry,2005,vol. 70,p. 1134 - 1146.

5
[ 189178-08-3 ]
[ 189178-09-4 ]

Yield	Reaction Conditions	Operation in experiment
87%	With water; sodium hydroxide; In tetrahydrofuran; at 20℃; for 18h;	In reference to FIG. 2, a third compound according to the present invention, arbitrarily called CL64, was also synthesized, according to diagram 2 below, by a Sonogashira triple coupling between trialkyne 4b (obtained by deprotection of 4a in a basic medium) and 3.5 equivalents of the iodized derivative 5.More specifically, an aqueous solution of NaOH (1 M, 30 mL) is added to a solution of the compound 4a (2.33 g, 4.36 mmol) in THF (30 mL), and the mixture is agitated vigorously at 20 C. for 18 h. After evaporation of the THF, dichloromethane is added. The organic phase is separated, washed with water and dried (Na2SO4). The residue obtained after removal of the solvent is purified by chromatography on a silica column (heptane/CH2Cl2 90:10, then 85:15) to produce 1.20 g (87%) of the compound 4b.The air is purged with a solution of compound 4b (17.9 mg, 0.056 mmol), compound 5 (100 mg, 0.197 mmol) and tri-o-furylphosphine (0.52 mg, 2.26 μmol) in 1.5 mL of toluene/Et3N (5/1) by argon bubbling for 30 min. Then, Pd2 dba3 (0.26 mg, 0.28 μmol) is added, and the mixture is agitated at 20 C. for 20 h. After evaporation of the solvent under reduced pressure, the raw product is purified by chromatography on a silica column (heptane/CH2Cl2 60:40, then 50:50) to produce 19 mg (24%) of CL64.

References: [1]Journal of Materials Chemistry C,2020,vol. 8,p. 10774 - 10780.
[2]Dalton Transactions,2006,p. 3693 - 3698.
[3]Angewandte Chemie - International Edition,2015,vol. 54,p. 12748 - 12752.
Angew. Chem.,2015,vol. 127,p. 12939 - 12943,4.
[4]Patent: US2009/221819,2009,A1 .Location in patent: Page/Page column 13.
[5]Chemistry - A European Journal,2012,vol. 18,p. 12487 - 12497.
[6]Chemistry - An Asian Journal,2013,vol. 8,p. 2984 - 3001.
[7]Angewandte Chemie - International Edition,2021,vol. 60,p. 11326 - 11334.
Angew. Chem.,2021,vol. 133,p. 11427 - 11435,9.
[8]Molecules,2022,vol. 27.
[9]Journal of Organic Chemistry,2005,vol. 70,p. 1134 - 1146.
[10]Tetrahedron Letters,2010,vol. 51,p. 521 - 524.
[11]New Journal of Chemistry,2016,vol. 40,p. 10246 - 10258.
[12]Chemical Communications,2013,vol. 49,p. 780 - 782.
[13]Patent: EP1170273,2002,A1 .Location in patent: Page 8.
[14]Journal of the American Chemical Society,2021,vol. 143,p. 16284 - 16292.
[15]Macromolecules,2010,vol. 43,p. 7577 - 7582.
[16]Journal of Organic Chemistry,2011,vol. 76,p. 8726 - 8736.
[17]Journal of Photochemistry and Photobiology A: Chemistry,2014,vol. 290,p. 22 - 30.
[18]Journal of Materials Chemistry C,2015,vol. 3,p. 7345 - 7355.
[19]Journal of Materials Chemistry C,2016,vol. 4,p. 2535 - 2544.
[20]Molecular Crystals and Liquid Crystals,2017,vol. 645,p. 1 - 9.
[21]Chemical Communications,2017,vol. 53,p. 8778 - 8781.
[22]RSC Advances,2017,vol. 7,p. 47681 - 47688.
[23]Green Chemistry,2019,vol. 21,p. 6606 - 6610.

6
[ 189178-09-4 ]
poly[tris(4-ethynylphenyl)amine], hyperbranched, M_w: 24100, polydispersity index: 1.6, temperature for 5 percent loss: 516 deg C, weight residue at 900 deg C: 78.0 percent; monomer(s): tris(4-ethynylphenyl)amine [ No CAS ]

References: [1]Journal of Physical Chemistry B,2004,vol. 108,p. 10645 - 10650.

7
[ 92874-17-4 ]
[ 189178-09-4 ]
4,4',4''-tri(N-butyl-4-ethynyl)-1,8-naphthalimide-triphenylamine [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
80%		In flame dried Schlenk flask (100 mL), <strong>[189178-09-4]tris(4-ethynylphenyl)amine</strong> (105.8 mg, 0.33 mmol), Pd(PPh3)4 (62.4mg, 0.054 mol), CuI (3.4mg, 0.018mmol), and anhydrous THF (10 mL) were charged under N2 atmosphere. After 30 min stirring, 4-bromo-1,8-napthalimide (328.9 mg,0.99 mmol) in anhydrous THF (20 mL) and Et3N (6 mL) were added. The mixture was stirred at room temperature overnight. After the starting materials were full reacted, as confirmed by TLC, the mixture was poured to distilled water 50mL. Then, it was extracted by dichloromethane (25 mL × 3). The organic phase dried over Mg2SO4 and evaporated in vacuum. The residue was loaded to the column. Column separation (silica gel 200-300 mesh,eluent: dichloromethane/petroleum = 2/1) produced 286 mg yellow powder (80%).Mp: 281-284C; IR (KBr, υ, cm-1): 780, 1085, 1235, 1274, 1319, 1353, 1503, 1511, 1587,1660, 1697, 2196, 2960. 1H NMR(400 MHz, CDCl3): δ (ppm): 8.73 (3H, d, J = 8.0 Hz), 8.65(3H, d, J = 8.0 Hz), 8.56 (3H, d, J = 8.0 Hz), 7.95 (3H, d, J = 8.0 Hz), 7.84 (3H, t, J = 8.0Hz), 7.64 (6H, d, J = 8.0 Hz), 7.23 (6H, d, J = 8.0 Hz), 4.20 (6H, t, J = 8.0 Hz), 1.73 (6H, m), 1.53-1.44 (6H, m), 0.99 (9H, t, J = 8.0 Hz). 13C NMR (100 MHz, CDCl3): δ (ppm): 164.1,163.9, 147.4, 133.5, 132.4, 131.73, 131.67, 130.7, 130.5, 128.2, 127.7, 127.6, 124.5, 123.2, 122.2,118.1, 117.5, 99.1, 86.8, 40.5, 30.4, 29.8, 20.6, 14.0.Maldi-Tof: [M+H]+ C72H56N4O5 requires1071.412; found [M+H]+ 1071.501; and [M+2H]+ C72H57N4O5 requires 1072.420; found1072.508 (Base).

References: [1]Molecular Crystals and Liquid Crystals,2017,vol. 645,p. 1 - 9.
[2]Chemistry Letters,2005,vol. 34,p. 922 - 923.

8
4-azido-N,N-dihexylbenzenamine [ No CAS ]
[ 189178-09-4 ]
C₇₈H₁₀₅N₁₃ [ No CAS ]

References: [1]Chemical Communications,2005,p. 2029 - 2031.

9
[ 4181-20-8 ]
[ 1066-54-2 ]
[ 189178-09-4 ]

References: [1]Journal of Fluorescence,2014,vol. 24,p. 197 - 202.
[2]Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals,2001,vol. 370,p. 207 - 210.
[3]Dyes and Pigments,2016,vol. 124,p. 101 - 109.

10
[ 189178-09-4 ]
polymer; monomer(s): tris(4-ethynylphenyl)amine [ No CAS ]

References: [1]Macromolecules,2004,vol. 37,p. 5196 - 5210.

11
[ 4316-58-9 ]
mono(6percent) and dibromo TBPA(2percent) [ No CAS ]
[ 189178-09-4 ]

References: [1]Dalton Transactions,2006,p. 3693 - 3698.

12
[ 4181-20-8 ]
[ 189178-09-4 ]

References: [1]Journal of Organic Chemistry,2005,vol. 70,p. 1134 - 1146.
[2]Journal of Organic Chemistry,2011,vol. 76,p. 8726 - 8736.
[3]Journal of Polymer Science, Part A: Polymer Chemistry,2011,vol. 49,p. 1830 - 1839.
[4]Chemistry - A European Journal,2012,vol. 18,p. 12487 - 12497.
[5]Chemical Communications,2013,vol. 49,p. 780 - 782.
[6]Chemistry - An Asian Journal,2013,vol. 8,p. 2984 - 3001.
[7]Angewandte Chemie - International Edition,2015,vol. 54,p. 12748 - 12752.
Angew. Chem.,2015,vol. 127,p. 12939 - 12943,4.
[8]Journal of Materials Chemistry C,2015,vol. 3,p. 7345 - 7355.
[9]Journal of Materials Chemistry C,2016,vol. 4,p. 2535 - 2544.
[10]Molecular Crystals and Liquid Crystals,2017,vol. 645,p. 1 - 9.
[11]Chemical Communications,2017,vol. 53,p. 8778 - 8781.
[12]RSC Advances,2017,vol. 7,p. 47681 - 47688.

13
[ 189178-09-4 ]
tris-4,4',4''-(4-carboxyphenylethynyl)triphenylamine [ No CAS ]

References: [1]Journal of Organic Chemistry,2005,vol. 70,p. 1134 - 1146.

14
[ 189178-09-4 ]
tris-4,4',4''-[N-(4-methyl)-4-pyridinioethynyl]triphenylamine trisiodide [ No CAS ]

References: [1]Journal of Organic Chemistry,2005,vol. 70,p. 1134 - 1146.

15
cis-[RuCl₂(dppe)2] [ No CAS ]
[ 189178-09-4 ]
(tri(4-ethynylphenyl)amine(-3H))[Ru(dppe)2Cl]3 [ No CAS ]

References: [1]Dalton Transactions,2006,p. 3693 - 3698.

16
[ 15636-79-0 ]
[ 189178-09-4 ]
[ 1007866-62-7 ]

References: [1]Organometallics,2008,vol. 27,p. 316 - 319.
[2]Organometallics,2009,vol. 28,p. 4288 - 4296.

17
[ 177595-61-8 ]
[ 189178-09-4 ]
tris-[4-(4-dimesitylborylphenylethynyl)phenyl]amine [ No CAS ]

References: [1]Chemistry - A European Journal,2009,vol. 15,p. 198 - 208.

18
[ 51458-06-1 ]
[ 189178-09-4 ]
[ 1127353-49-4 ]

References: [1]Chemistry - A European Journal,2009,vol. 15,p. 198 - 208.

19
[ 53694-87-4 ]
[ 189178-09-4 ]
[ 943154-17-4 ]

Yield	Reaction Conditions	Operation in experiment
22%	With triethylamine;tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane; In toluene; at 20℃; for 20h;Inert atmosphere;	Synthesis of 4-[(4-azidophenyl)ethynyl]-N,N-bis[4-[(4-azidophenyl)ethynyl]phenyl]-benzenamine (11) In reference to , this compound was synthesised, according to diagram 5 below. The air is purged from a solution of 4-ethynyl-N,N-bis(4-ethynylphenyl)benzenamine (4b), (64 mg, 0.202 mmol), 1-azido-4-iodo-benzene (10) (197.6 mg, 0.807 mmol) and tri-2-furylphosphine (2 mg, 8.6 micromol) in 6 mL of toluene/Et3N (5/1) by argon bubbling for 30 min. Then, tris(dibenzylideneacetone)-dipalladium (0) (11 mg, 12 micromol) is added and the mixture is agitated at 20 C. for 20 h. After evaporation of the solvent under reduced pressure, the raw product is purified by chromatography on a silica column (heptane/CH2Cl2 80:20) to produce 30 mg (22%) of 11.

References: [1]Patent: US2009/221819,2009,A1 .Location in patent: Page/Page column 13; 14.

20
2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8-(4-iodophenyl)-4-bora-3a,4a-diaza-s-indacene [ No CAS ]
[ 189178-09-4 ]
[ 943154-15-2 ]

Yield	Reaction Conditions	Operation in experiment
24%	With triethylamine;tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane; In toluene; at 20℃; for 20h;Inert atmosphere;	In reference to FIG. 2, a third compound according to the present invention, arbitrarily called CL64, was also synthesized, according to diagram 2 below, by a Sonogashira triple coupling between trialkyne 4b (obtained by deprotection of 4a in a basic medium) and 3.5 equivalents of the iodized derivative 5.More specifically, an aqueous solution of NaOH (1 M, 30 mL) is added to a solution of the compound 4a (2.33 g, 4.36 mmol) in THF (30 mL), and the mixture is agitated vigorously at 20 C. for 18 h. After evaporation of the THF, dichloromethane is added. The organic phase is separated, washed with water and dried (Na2SO4). The residue obtained after removal of the solvent is purified by chromatography on a silica column (heptane/CH2Cl2 90:10, then 85:15) to produce 1.20 g (87%) of the compound 4b.The air is purged with a solution of compound 4b (17.9 mg, 0.056 mmol), compound 5 (100 mg, 0.197 mmol) and tri-o-furylphosphine (0.52 mg, 2.26 μmol) in 1.5 mL of toluene/Et3N (5/1) by argon bubbling for 30 min. Then, Pd2 dba3 (0.26 mg, 0.28 μmol) is added, and the mixture is agitated at 20 C. for 20 h. After evaporation of the solvent under reduced pressure, the raw product is purified by chromatography on a silica column (heptane/CH2Cl2 60:40, then 50:50) to produce 19 mg (24%) of CL64.

References: [1]Patent: US2009/221819,2009,A1 .Location in patent: Page/Page column 13.

21
3,5-bis((E)-2-phenylethenyl)-8-(4-iodophenyl)-4,4'-difluoroboroadiazaindacene [ No CAS ]
[ 189178-09-4 ]
C₁₁₇H₇₈B₃F₆N₇ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
58%	With triethylamine;tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane; In toluene; at 20℃; for 15h;Inert atmosphere;	In reference to FIG. 6, a seventh compound according to the present invention, arbitrarily called MC297, was synthesized according to diagram 6 below.The air is purged from a solution of 3,5-bis((E)-2-phenylethenyl)-8-(4-iodophenyl)-4,4'-difluoroboroadiazaindacene (17) (105 mg, 0.176 mmol), 4-ethynyl-N,N-bis(4-ethynylphenyl)-benzenamine (4b) (15.9 mg, 0.050 mmol) and tri-2-furylphosphine (0.5 mg, 2.15 micromol) in 2 mL of toluelle/Et3N (5/1) by argon bubbling for 20 min. Then, tris(dibenzylideneacetone)-dipalladium (0) (2.8 mg, 3.06 micromol) is added and the mixture is agitated at 20 C. for 15 h. After evaporation of the solvent under reduced pressure, the raw product is purified by chromatography on a silica column (heptane/CH2Cl2 70:30, 50/50 then pule CH2Cl2) to produce 50 mg (58%) of MC303.

References: [1]Patent: US2009/221819,2009,A1 .Location in patent: Page/Page column 14.

22
[ 368455-15-6 ]
[ 189178-09-4 ]
[ 1173285-12-5 ]

References: [1]Journal of the American Chemical Society,2009,vol. 131,p. 9186 - 9188.

23
[ 1207158-64-2 ]
[ 189178-09-4 ]
[ 1207158-63-1 ]

References: [1]Tetrahedron Letters,2010,vol. 51,p. 521 - 524.

24
[ 259145-15-8 ]
[ 189178-09-4 ]
[ 1207158-62-0 ]

References: [1]Tetrahedron Letters,2010,vol. 51,p. 521 - 524.

25
[ 609770-35-6 ]
[ 189178-09-4 ]
[ 1267583-47-0 ]

References: [1]Chinese Journal of Chemistry,2010,vol. 28,p. 2226 - 2232.

26
[ 654070-00-5 ]
[ 189178-09-4 ]
[ 1338574-43-8 ]

References: [1]Journal of Organic Chemistry,2011,vol. 76,p. 8726 - 8736.

27
[ 1123-99-5 ]
[ 189178-09-4 ]
[ 1338574-48-3 ]

References: [1]Journal of Organic Chemistry,2011,vol. 76,p. 8726 - 8736.

28
[ 1025452-30-5 ]
[ 189178-09-4 ]
[ 1338574-49-4 ]

References: [1]Journal of Organic Chemistry,2011,vol. 76,p. 8726 - 8736.

29
[ 1338574-28-9 ]
[ 189178-09-4 ]
[ 1338574-44-9 ]

References: [1]Journal of Organic Chemistry,2011,vol. 76,p. 8726 - 8736.

30
[ 603-34-9 ]
[ 189178-09-4 ]

References: [1]Journal of Organic Chemistry,2011,vol. 76,p. 8726 - 8736.
[2]Journal of Polymer Science, Part A: Polymer Chemistry,2011,vol. 49,p. 1830 - 1839.
[3]Journal of Materials Chemistry C,2015,vol. 3,p. 7345 - 7355.
[4]Molecular Crystals and Liquid Crystals,2017,vol. 645,p. 1 - 9.
[5]Chemical Communications,2017,vol. 53,p. 8778 - 8781.
[6]RSC Advances,2017,vol. 7,p. 47681 - 47688.
[7]Angewandte Chemie - International Edition,2021,vol. 60,p. 11326 - 11334.
Angew. Chem.,2021,vol. 133,p. 11427 - 11435,9.

31
sodium hexaflorophosphate [ No CAS ]
cis-[RuCl₂(dppe)2] [ No CAS ]
[ 189178-09-4 ]
trans,trans,trans-[(Ru(CCH-4-C₆H₄)Cl(1,2-bis(diphenylphosphanyl)ethane)2)3N][PF₆]3 [ No CAS ]

References: [1]European Journal of Inorganic Chemistry,2012,p. 65 - 75.

32
4,4',4''-(4,40',4''-nitrilotris(benzene-4,1-diyl))tris(2-methylbut-3-yn-2-ol) [ No CAS ]
[ 189178-09-4 ]

References: [1]European Journal of Inorganic Chemistry,2012,p. 65 - 75.
[2]Journal of Polymer Science, Part A: Polymer Chemistry,2011,vol. 49,p. 1830 - 1839.

33
[ 1360629-98-6 ]
[ 189178-09-4 ]
3,3',3''-(4,4',4''-(4,4',4''-(4,4',4''-nitrilotris(benzene-4,1-diyl))-tris(1H-1,2,3-triazole-4,1-diyl))tris(2,5-bis(hexyloxy)benzene-4,1-diyl))tris(2-cyanoacrylic acid) [ No CAS ]

References: [1]Dyes and Pigments,2012,vol. 94,p. 28 - 33.

34
[ 15636-79-0 ]
[ 189178-09-4 ]
[ 1007866-64-9 ]

References: [1]Organometallics,2008,vol. 27,p. 316 - 319.

35
[ 17084-13-8 ]
(1,2,3,4,5-pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)iron(II)Cl [ No CAS ]
[ 189178-09-4 ]
[((η2-dppe)(η5-C5Me5)Fe=C=CH-1,4-C6H4)3N][PF6]3 [ No CAS ]

References: [1]Organometallics,2012,vol. 31,p. 1635 - 1642.

Historical Records

Technical Information

• Benzylic Oxidation • Birch Reduction • Blanc Chloromethylation • Buchwald-Hartwig C-N Bond and C-O Bond Formation Reactions • Chan-Lam Coupling Reaction • Friedel-Crafts Reaction • Hydride Reductions • Hydrogenolysis of Benzyl Ether • Leuckart-Wallach Reaction • Mannich Reaction • Petasis Reaction • Preparation of Alkylbenzene • Preparation of Amines • Reactions of Amines • Reactions of Benzene and Substituted Benzenes • Specialized Acylation Reagents-Vilsmeier Reagent • Ugi Reaction • Vilsmeier-Haack Reaction

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[ 189178-09-4 ]

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P280	Wear protective gloves/protective clothing/eye protection/face protection.
P281	Use personal protective equipment as required.
P282	Wear cold insulating gloves/face shield/eye protection.
P283	Wear fire/flame resistant/retardant clothing.
P284	Wear respiratory protection.
P285	In case of inadequate ventilation wear respiratory protection.
P231 + P232	Handle under inert gas. Protect from moisture.
P235 + P410	Keep cool. Protect from sunlight.
Response
Code	Phrase
P301	IF SWALLOWED:
P304	IF INHALED:
P305	IF IN EYES:
P306	IF ON CLOTHING:
P307	IF exposed:
P308	IF exposed or concerned:
P309	IF exposed or if you feel unwell:
P310	Immediately call a POISON CENTER or doctor/physician.
P311	Call a POISON CENTER or doctor/physician.
P312	Call a POISON CENTER or doctor/physician if you feel unwell.
P313	Get medical advice/attention.
P314	Get medical advice/attention if you feel unwell.
P315	Get immediate medical advice/attention.
P320
P302 + P352	IF ON SKIN: wash with plenty of soap and water.
P321
P322
P330	Rinse mouth.
P331	Do NOT induce vomiting.
P332	IF SKIN irritation occurs:
P333	If skin irritation or rash occurs:
P334	Immerse in cool water/wrap n wet bandages.
P335	Brush off loose particles from skin.
P336	Thaw frosted parts with lukewarm water. Do not rub affected area.
P337	If eye irritation persists:
P338	Remove contact lenses, if present and easy to do. Continue rinsing.
P340	Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P341	If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P342	If experiencing respiratory symptoms:
P350	Gently wash with plenty of soap and water.
P351	Rinse cautiously with water for several minutes.
P352	Wash with plenty of soap and water.
P353	Rinse skin with water/shower.
P360	Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P361	Remove/Take off immediately all contaminated clothing.
P362	Take off contaminated clothing and wash before reuse.
P363	Wash contaminated clothing before reuse.
P370	In case of fire:
P371	In case of major fire and large quantities:
P372	Explosion risk in case of fire.
P373	DO NOT fight fire when fire reaches explosives.
P374	Fight fire with normal precautions from a reasonable distance.
P376	Stop leak if safe to do so. Oxidising gases (section 2.4) 1
P377	Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P378
P380	Evacuate area.
P381	Eliminate all ignition sources if safe to do so.
P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
P301 + P310	IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P301 + P330 + P331	IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
P303 + P361 + P353	IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360	IF ON CLOTHING: Rinse Immediately contaminated CLOTHING and SKIN with plenty of water before removing clothes.
P307 + P311	IF exposed: call a POISON CENTER or doctor/physician.
P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
P371 + P380 + P375	In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
Storage
Code	Phrase
P401
P402	Store in a dry place.
P403	Store in a well-ventilated place.
P404	Store in a closed container.
P405	Store locked up.
P406	Store in corrosive resistant/ container with a resistant inner liner.
P407	Maintain air gap between stacks/pallets.
P410	Protect from sunlight.
P411
P412	Do not expose to temperatures exceeding 50 oC/ 122 oF.
P413
P420	Store away from other materials.
P422
P402 + P404	Store in a dry place. Store in a closed container.
P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
P403 + P235	Store in a well-ventilated place. Keep cool.
P410 + P403	Protect from sunlight. Store in a well-ventilated place.
P410 + P412	Protect from sunlight. Do not expose to temperatures exceeding 50 oC/122oF.
P411 + P235	Keep cool.
Disposal
Code	Phrase
P501	Dispose of contents/container to ...
P502	Refer to manufacturer/supplier for information on recovery/recycling

Physical hazards
Code	Phrase
H200	Unstable explosive
H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
H203	Explosive; fire, blast or projection hazard
H204	Fire or projection hazard
H205	May mass explode in fire
H220	Extremely flammable gas
H221	Flammable gas
H222	Extremely flammable aerosol
H223	Flammable aerosol
H224	Extremely flammable liquid and vapour
H225	Highly flammable liquid and vapour
H226	Flammable liquid and vapour
H227	Combustible liquid
H228	Flammable solid
H229	Pressurized container: may burst if heated
H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
H272	May intensify fire; oxidizer
H280	Contains gas under pressure; may explode if heated
H281	Contains refrigerated gas; may cause cryogenic burns or injury
H290	May be corrosive to metals
Health hazards
Code	Phrase
H300	Fatal if swallowed
H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
H304	May be fatal if swallowed and enters airways
H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
H317	May cause an allergic skin reaction
H318	Causes serious eye damage
H319	Causes serious eye irritation
H320	Causes eye irritation
H330	Fatal if inhaled
H331	Toxic if inhaled
H332	Harmful if inhaled
H333	May be harmful if inhaled
H334	May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335	May cause respiratory irritation
H336	May cause drowsiness or dizziness
H340	May cause genetic defects
H341	Suspected of causing genetic defects
H350	May cause cancer
H351	Suspected of causing cancer
H360	May damage fertility or the unborn child
H361	Suspected of damaging fertility or the unborn child
H361d	Suspected of damaging the unborn child
H362	May cause harm to breast-fed children
H370	Causes damage to organs
H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
H373	May cause damage to organs through prolonged or repeated exposure
Environmental hazards
Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

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CAS No.: 189178-09-4

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